Theory Into Practice

In January, we were clueless on what “Design for Environment” really is. It seems like a good title for a new elective so it may be worthwhile taking it. But the moment we sit on this class, our perspective of the chemical process has changed.

We first learned about the problem all of us humans are facing in the future such as overpopulation, the rapid decrease and inefficient of natural resources, the degradation of lands and seas, and the prevalent crisis in energy. And we hear this word “sustainability”, the abandonment of use of non-renewable resources, and the decrease of use of renewable resources such that it is in line with natural processes. That is when we became talked about the plant and product life cycle.

Other than that, we then talked about the green chemistry principles such that we must apply if we want to make a product that is not dangerous to make whether by synthesis or material, cheap, efficient in heat, and optimized. Not only that, we are made aware of the metrics such as the E-factor, atom utilization, relative mass and element efficiency.

We also characterize the risk of making a product from the plant to the environment. From that, we devise ways and alternatives to reduce this risk by assessing the reactors in order to minimize pollution to the environment. We also talk about world governments taking action in addressing environmentally harmful chemicals like the Montreal Protocol.

We also reduce wasted streams and heat by process integration. We assess the effect of these wastes to the environment by computing how fast it decays, how it is readily adsorbed by the soil, and how living organisms react to it.

Since we also look at the plant, we look at how it gets its power from different resources. The current paradigm is a shift to renewable energy but most of our energy infrastructure is towards fossil fuels that is why countries strategize energy policies and plans for the future.

Not to be outdone, the product is on the spotlight with its life cycle analysis. We analyze the production process to what product is to which process and the impact of the product to the consumer, from then on we develop, regulate, plan and market for the product but first, goals, scope, specifics, organization and procedures are to be done. This is made to weigh the options of the decision maker if which has a greater impact to the environment.

All in all, it comes down to cost. From production costs to administrative and regulatory costs to liability cost to cost that can that affect inside and outside the company, we give every single nook and cranny of the company value.

We look to the future and dream of industries work hand in hand with one industry’s waste another industry’s material and we can see the first glimpse from Denmark to here at Clark. We also look at the growth of the industry especially in developing countries and a paradigm shift from taking things for granted to looking towards sustainability with thrusts for new raw materials, new algorithms, and the use of organisms in making new polymers and as a catalyst in process reactions.

Now that we have blessed with this knowledge for the past 5 months, we can apply them to our future careers as an engineer and as a resident of our one and only home. We hope that what we can learn can change the course of our environment that we sometimes cherish and neglect.

A Simple Application of LCA: Does Organic Mean Sustainable?

With our fast-paced world, commodities are being manufactured at an equally fast pace. To shorten time spent on preparing various products while reaching standards and satisfying the consumers, industries have invested in different techniques and the creation and development of new raw materials. In the case of the food industry, traditional farming practices have been modified to sustain the growing population of the world, while increasing its quality and battling the obstacles that are inherent to this industry. The now conventional farming methods are employing pesticides, fertilizers, and other chemicals to. Some companies are also delving into the use of GMOs (genetically modified organism) that are resistant to certain diseases and conditions, and with added properties depending on the demand of the market (e.g. Vitamin A in rice, seedless fruits, hybrid species of plants). Despite the vast improvement in the overall quality of food and the undeniable massive rate of production, the rekindling of the traditional method, or organic farming, is being promoted by different groups for different reasons. Some say that organic products are healthier, others say that it is friendlier to the environment, but this are more expensive products thus, the market for organic food are sometimes limited to those who could afford it. But is the claim to fame of organic foods going to be enough for the future population? We cannot help but wonder if the additional cost for these products can be considered a sound investment for the future or if it is just an unnecessary burden to the consumers.

In the US, the term “organic” may only be used on products that have at least 95 percent organic. The “100 percent organic” seal is used for products that are “completely organic or made of all organic ingredients (Mayo Clinic).” Organic farming, according to (Mayo Clinic), “refers to the way farmers grow and process agricultural products, such as fruits, vegetables, grains, dairy products and meat. Organic farming practices are designed to encourage soil and water conservation and reduce pollution.” The methods of organic farming remove the use of artificial fertilizers, artificial pesticides, hormones, antibiotics, bioengineering, and other artificial chemicals and methods.

Advantages of organic products over those that are harvested through conventional methods are minimal to no pesticide residue, absence of additives, and least impact to the environment. Pesticide use in the conventional method may have diminished the pest, and subsequently, increased the output greatly, but then insects and weeds are becoming resistant to these through the years. Although meant to improve the quality of food products (through artificial preservatives, flavorings, etc.), additives may also be used to meet cheat/pass standards. An example is the addition of melamine in protein-deficient milk in China to be able to pass quality tests in 2008.  The synthetic additives are also under fire due to some research findings that these are actually bad for the health. Organic farming is also supposed to be better for the environment, as it eliminates the introduction of non-natural chemicals to the environment, reduces pollution, and conserves water and soil. The downsides? Its cost-effectiveness, efficiency, and “authenticity”. The conventional method ensure a high harvest yield while maintaining uniformity in the products, while organic farming cannot promise consistency as the produce are dependent only to soil and water only. Natural fertilizers and pesticides are not as efficient compared to its artificial counterpart (Mayo Clinic). The truth whether organic products are really environmentally friendly is also questioned. It has been noted by (Zelman) that the variable quantity and quality of organic products may be problematic as this may also need more land area, just to meet similar quantities with the conventional method. Subsequently, more resources (e.g. water, natural fertilizers, and natural pesticides) would also be required.

To give us an idea on the current studies on evaluating the sustainability of organic farming, different life cycle assessments are going to be cited.  From the journal article “Comparing of Twelve Organic and Conventional Farming Systems: A Life Cycle Greenhouse Gas Emissions Perspective” by Kumar Venkat, twelve distinct crop products are used, namely: blueberries, two apples, two wine grapes, raisin grapes, strawberries, alfalfa for hay, almonds, walnuts, broccoli, and lettuce. A comparison of the cradle-to-farm gate greenhouse gas emission per kilogram of each crop production was used. The conclusion of the study states that only five out of the twelve crops has lower emissions using the organic farming method, while the conventional has seven out of twelve crops with lower emissions. The study has stated the following possible reasons: “lower yields and higher on-farm energy use in organic farming, the production and delivery of large quantities of compost in some organic systems, and the fact that emissions from the manufacture of synthetic fertilizers and pesticides used in conventional farming are not large enough to offset the additional emissions in organic farming.” Although it was noted that the transitional phase from conventional to organic farming had seven out of twelve lower cases, the organic farming failed to prove that its greenhouse gas emissions is lower, thus a better alternative to conventional farming procedures.

However, the article of Meier, Stoessel and Jungbluth concludes that they were not able to consolidate the thirty four reviewed LCA studies to create a comparison on the general environmental performance of the two farming systems. It said that there were no distinction on what is organic and conventional farming on the inventory level. Some assumptions were also simplified but became invalid due to the effect of the adjusted parameters.

Another study, done by the group of Thomassen, Calker and Smits, assessed the conventional and organic milk production in Netherlands. The general observation in the study was that the organic farming fared better with the given parameters. There were ten conventional farms and 11 organic farms in the study that were compared in terms of energy use and eutrophication potential per kilogram of milk, and in both cases, the organic farming system showed lower results. However, more ammonia, methane, and nitrous oxide emissions were observed per kilogram organic milk than for conventional mil. Land use was also efficient for conventional farming system. No significant difference were seen between the two methods for the total acidification potential and global warming potential per kilogram milk.

To sum it all up, there are many parameters that are needed to be considered before one can conclude which method is better in terms of environmental impact. More LCA and a concentrated topic should also be ensured to minimize discrepancies in the studies. So for now, there is not enough unity in the LCAs available to conclude that the organic farming system is indeed the better alternative for sustainability. For unsure consumers, Zelman suggests that a combination of the products of the two types should be bought, as long as the products are in season and are grown locally, to at least minimize carbon footprint brought by the transport.

References

Mayo Clinic. Organic foods: Are they safer? More nutritious? 9 June 2014. Report. 28 April 2015. <http://www.mayoclinic.org/healthy-lifestyle/nutrition-and-healthy-eating/in-depth/organic-food/art-20043880?pg=1&gt;.

Meier, Matthias S., et al. “Environmental impacts of organic and conventional agricultural products – Are the differences captured by life cycle assessment?” Journal of Environmental Management (2015): 193-209. Web.

Thomassen, M.A., et al. “Life cycle assessment of conventional and organic milk production in the Netherlands.” Agricultural Systems (2007): 95-107. Web.

Venkat, Kumar. “Comparison of Twelve Organic and Conventional Farming Systems: A Life Cycle Greenhouse Gas Emissions Perspective.” Journal of Sustainable Agriculture (2012): 620-649. Web.

Zelman, Kathleen M. Organic Food – Is ‘Natural’ Worth The Cost? 10 August 2007. Report. 28 April 2015. <http://www.webmd.com/food-recipes/organic-food-is-natural-worth-the-extra-cost?page=1&gt;.

Life Cycle Assessment Throughout the Years

By simple deduction, we can quickly understand what “life cycle assessment” (LCA) refers to. In basic terms, this is the determination of the importance, size, or value (“assess”) of the life cycle of practically anything produced from its origins to its end state. This end state may be a state of waste/disposed matter or a state of reuse/recycle/remanufacture/etc.

We’ll cover the specifics of a typical general life cycle assessment of any given product in a future blog post. For now, we’ll just be tackling general information on what LCA’s are and (for the most part) how LCA’s came about and developed throughout the years.

We can start by looking back to the 1960’s and 1970’s when studying the impact of consumer products to the environment started to become a big deal. Due to one product trying to best its competition in any way it can, environmental impact discussion on consumer products grew to long and sometimes fierce debates (Hocking, 1991). Take a look at some examples, as given by Guinée et al (2011), and see if they do fit in this situation:

Fluorescent_lamps_artistic vs. Gluehlampe_01_KMJ

shatto-milk-glass-bottles vs. att61a9 vs. milk_carton1

As far as environmental impact is concerned, further investigations and explorations revealed that a product mostly affects its environment during its production, transportation, or disposal, and not when it is being used by the consumer (Guinée et al, 2011). This finding eventually became a bigger issue, and a way for it to be addressed has to be done. This is where LCA comes in, which ISO 14040 and ISO 14044 define as the:

“…compilation and evaluation of the inputs and outputs and the potential environmental impacts of a product system throughout its life cycle”

The continual adaptation of the concept in the scientific and engineering community can be seen in the increasing number of LCA literature in Environmental Science Technology, a well-known and reputable journal dealing with, well, environmental science:

Histogram of the number of articles mentioning LCA in ES&T showing the emergence of LCA in particularly the 1990's, starting from the first issue of ES&T in 1967 (Source: ACS Publication ES&T Web site, obtained from Guinée et al's 2011 paper as cited below)

Histogram of the number of articles mentioning LCA in ES&T showing the emergence of LCA in particularly the 1990’s, starting from the first issue of ES&T in 1967 (Source: ACS Publication ES&T Web site, obtained from Guinée et al’s 2011 paper as cited below)

Clearly, scientists and engineers realized as time went by the importance of LCA’s in ultimately minimizing, if not eliminating, the hazardous environmental impacts a consumer product may cause all throughout its life cycle.

Jacquemin et al presented in a 2012 paper of theirs a handy diagram showing the general approach of industries to environmental issues during various time periods. This diagram places LCA under pollution and waste approaches that started in the 1990’s. They stated that the LCA approach is a proactive approach which eventually became a progressive one at the turn of the following decade. At this time period (the 2000’s), LCA has been said to be generalized and aided also by the development of integrated tools for environmental design and evaluation of industrial processes. This diagram is shown below:

Industrial response to environmental issues (Jacquemin et al, 2012)

Industrial response to environmental issues (Jacquemin et al, 2012)

A better timeline-based perspective of LCA’s development was presented by Guinée et al. In their 2011 paper, they divided the state of LCA into past (1970-2000), present (2000-2010), and future (2010-2020) stages. Listed below are the subdivisions and key points of these stages. More can be read in their paper (as listed in the References section below).

The Past of LCA (1970-2000)

1970-1990: Decades of Conception

  • Environmental issues like resource and energy efficiency, pollution control, and solid waste became issues of broad public concern, and a solution to these issues has to be conceptualized and eventually implemented as soon as possible.
  • The Midwest Research Institute (MRI) conducted an unpublished study quantifying the resource requirements, emission loadings, and waste flows of different Coca Cola beverage containers.
  • MRI’s study was termed as a “Resource and Environmental Profile Analysis” (REPA), and this practically served as the precursor of the current LCA.
  • Since the LCA was still at its early periods of conceptualization, widely diverging approaches, terminologies, and results materialized.

1990-2000: Decade of Standardization

  • Started with the convergence of the Society of Environmental Toxicology and Chemistry’s (SETAC) “Code of Practice” (aimed towards the leading and coordination of LCA practitioners, users, and scientists for the continuous improvement and harmonization of of LCA frameworks, terminologies, and methodologies) and the International Organization for Standardization’s (ISO) formal task of standardization of methods and procedures via the ISO 14040 and ISO 14044.
  • LCA became part of policy documents and legislation.

The Present of LCA: Decade of Elaboration (2000-2010)

  • Divergence in methods became prevalent due to the need for robustness.
  • Diverging approaches have been developed with respect to system boundaries and allocation methods, dynamic LCA, spatially differentiated LCA, risk-based LCA, and environmental input-output based LCA.
  • Life cycle costing and social life cycle assessment approaches have been proposed and/or developed that may have consistency problems with environmental LCA in terms of system boundaries, time perspectives, calculation procedures, etc.
  • There is a need for structuring the varying field of LCA approaches while taking into account more types of externalities and more mechanisms.

The Future of LCA: Decade of Life Cycle Sustainability Analysis (LCSA) [2010-2020]

  • The Coordination Action for Innovation in Life Cycle Analysis for Sustainability (CALCAS) project was commissioned by the European Commission.
  • CALCAS’ purpose was to structure the varying field of LCA approaches and to define research lines and programs to further LCA where necessary.
  • The LCSA resulted from CALCAS.
  • The framework of LCSA links life cycle sustainability questions to knowledge needed for addressing them, identifying available knowledge and related models, knowledge gaps, and defining research programs to fill these gaps.
  • Three important differences with the ISO 14040: (1) the merging of inventory analysis and impact assessment into one modeling phase, (2) the broadening of the object of analysis, and (3) the broadening of the scope of indicators.

True enough, scientists and engineers have been working tirelessly to improve LCA’s so as to properly obtain their specific and overall end goals. It really is amazing to know about its beginnings and to witness how it still develops. The best we can get from all this is that if much time, effort, and ideas are being dedicated to the improvement of LCA’s, then experts really find LCA’s to be very beneficial in designing for the environment. If anything else, the history of LCA’s should serve as a motivation for us to learn more about how LCA’s are conducted. After all, if it has been established that most products affect the environment in those parts of their life cycles not directly involving the consumer, then determining and assessing what happens to the product and to the materials/processes/etc. involved in its life cycle should prove to be sensible and worthwhile.

Stay tuned to our blog for more posts on LCA’s.

References! Get your references here!

Guinée, J. B., Zamagni, A., Masoni, P. et al. Life cycle assessment: past, present, and future. Environ. Sci. Technol. 2011, 45, 90–96.

Hocking, M. B. Paper versus polystyrene: a complex choice. Science 1991, 251 (4993), 504–505.

ISO 14040 International Standard. Environmental management – Life cycle assessment – Principles and framework; International Organization for Standardization: Geneva, Switzerland, 2006.

ISO 14044 International Standard. Environmental management – Life cycle assessment – Requirements and guidelines; International Organization for Standardization: Geneva, Switzerland, 2006.

Jacquemin, L., Pontalier, P., & Sablayrolles, C. Life cycle assesment (LCA) applied to the process industry: a review. Int. J. Life Cycle Assess. 2012, 17, 1028-1041.

The Argument with Nuclear Energy

Nuclear power is the production of energy and electricity from radioactive elements such as uranium. Nuclear power is a product of war. In the 1940’s, warring nations had developed nuclear weapons just for the sake of ultimate destruction to their enemy. This is demonstrated when the US, having finished their Manhattan Project, bombed Hiroshima and Nagasaki using uranium and plutonium bombs. After that, nations such as the US and the Soviet Union agreed that nuclear energy would be used for peaceful purposes and as a justification for government defense spending. This was emphasized in Dwight Eisenhower’s Atoms for Peace speech at the UN and from then on reactor technology was declassified from the US government.

Source: http://upload.wikimedia.org/wikipedia/commons/4/4e/Nuclear_Power_Plant_Cattenom.jpg

Fig 1. Cattenom Nuclear Power Plant in France

From 300 GW of nuclear energy capacity in the mid 1980’s, nuclear energy production slowed down to just 375 GW in the early 2010’s. The stagnation of nuclear energy is brought by:

  • high capital costs which would amount to 74% of the leveled cost of electricity for a new nuclear power plant,
  • proliferation of nuclear weapons to which even though there is a set treaty for peaceful use of nuclear energy (Nuclear Non-Proliferation Treaty), India, Pakistan, Israel and North Korea haven’t signed such treaty and may even be developing nuclear weapons on their own,
  • the complicated and/or absent waste management to which spent fuel is reprocessed into plutonium or dumped in isolated chambers and left there to decay for thousands of years, and lastly,
  • the nuclear accidents such as Chernobyl and Fukushima Daiichi which left an exclusion zone wherein no man can enter because the land itself emits harmful radiation from the ground and from the air.
Fig 2. Fukushima Daiichi Exclusion Zone

Fig 2. Fukushima Daiichi Exclusion Zone

With all the furor coming from the anti-nuclear movement and the governments of Japan and Germany giving in on the pressure of closing down nuclear plants, do we really have to abandon nuclear energy?

Figure 3. Japan’s monthly electric generation from 2009 to 2014

Figure 3. Japan’s monthly electric generation from 2009 to 2014

Because of the disaster, the Japanese government enacted a total preventive shutdown of all their nuclear power plants, hence their reliance on oil and gas has risen considerably.

Germany’s rapid Energiewende or energy revolution, with its focus on renewable energy (35% of the total energy production by 2020) and total nuclear-energy phaseout by 2022, has taken a toll to the consumers and to the industry as electricity prices have become 60% higher in the past 5 years (double the prices in the US), pushing companies like BASF to diversify its investments to other countries (in other words, reducing its focus from its country of origin). Added to that is the increase in GHG emissions because electric companies resort to coal as a result of the policy of accelerated nuclear phase-out.

Then why do we even try to kill it when we have to transform the whole grid with the sources power potential varying in weather and time? Besides that, nuclear energy has prevented 1.84 million deaths from air pollution and 64 GT on carbon dioxide GHG emissions from burning fossil fuels. Sounds ironic that we see the perspective of nuclear disasters (Fukushima Daiichi has no deaths, just an evacuation of 320 thousand people) when we have to look at the amount of people dying from toxic gases and the fact that we are aware that carbon dioxide emissions are the main cause of man-made climate change yet we have to keep on pumping it into the air just to satisfy our needs.

This brings us to the last argument which is the use of thorium. Thorium, with an atomic number 90, is a radioactive actinide with isotope 232 being the most abundant. It has a half-life of 1.405 x 1010 years and it is used as an alloy electrode and a light source in gas mantles but it is largely scrapped because it is radioactive. It is more abundant than uranium (10 ppm vs 2.5 for raw uranium), it is hard to turn into a nuclear weapon, it produces less waste (1 ton for Th vs 35 tons for U per 1 GW of electricity), it is more manageable (300 years isolation for Th vs. 10000 years for U), and it is more dense in energy than uranium (1 ton of Th energy = 200 tons U energy = 3.5 million tons coal energy).

In designing a thorium reactor, the process fluid is a chemically stable liquid (thorium fluoride) which needs no further enrichment, the operation is at atmospheric pressure, containment is smaller because the fluid turns into a solid if operation stops, and there is no need of control rods or a shutdown for refueling. Compare that to a uranium reactor that its fuel (uranium oxide) is chemically unstable, its design is inherently unsafe, with water at 70 atm as its main component in the design.

So why aren’t we using it?

To the words of Alvin Weinberg, the administrator of the Oak Ridge National Laboratory from 1955-1973, to which he designed the basis of both thorium and uranium reactors, said that it is a matter of politics and a change in paradigm. During his time, his first patented design, the uranium reactor, has already been established as the go-to design for the Nixon administration, the Atomic Energy Commission, and subsequently, all nuclear reactors until today. Also, the fact that you have to waste tons of money just to invest in a different and seemingly difficult to grasp technology is not appealing to investors who want short-term profits. Lastly, and most importantly, we have to change what we think. Nowadays, all we focus on is money, the status quo, and self-interest, not at our future. Those who do not agree to the powerful and to the rich may have to silence themselves, as what was done by Alvin Weinberg.

We end our journal entry for this week with a plea to spark a new discussion about energy. With climate change already in the works and our energy consumption going higher and higher, we should not abandon nuclear energy, or a better option would be create a new, inherently safe, cleaner, and efficient technology such as thorium reactors. We must not look at money but our future as a civilization. Do we take a leap or stand and let the ground crumble?

Links Links Links!

http://www.wsj.com/articles/germanys-expensive-gamble-on-renewable-energy-1409106602

http://pubs.acs.org/doi/abs/10.1021/es3051197?source=cen

https://www.youtube.com/watch?v=WWUeBSoEnRk&sn

http://www.reddit.com/r/science/comments/20b7v9/science_ama_series_were_professors_in_the/

http://www.ews-schoenau.de/fileadmin/content/documents/100GG/100_good_reasons.pdf

Images courtesy of Wikimedia Commons

How Far Can It Go?

For the past weeks, this blog has discussed pollution prevention through source reduction, recycle/reuse, treatment, storage, and disposal. In plant settings, the implementation of pinch technology greatly minimizes the use of additional resources. The use of heat exchanger networks diminishes the need for the manufacturing of additional heat exchangers and/or the need for more energy input. The use of mass exchanger networks optimizes the raw materials needed (specifically, fresh water in various class examples) and reduces waste generation through recycling at the pinch point. But what if waste generation cannot be prevented? After all, not all plants can implement a zero-waste program due to economic issues. Sometimes, not having a recycle stream in the process is cheaper in terms of profitability, although payment may be in the form of environmental degradation. There are many considerations needed in balancing the business-mindedness and the environment-mindedness of the plant, and these include the environmental fate and transport of the waste generated. Read More

Step by Step: Waste Minimization in Douglas’ Hierarchy of Process Synthesis

The most obvious and “basic” way one can quickly think of when it comes to minimizing the waste generated by a chemical plant is to improve the plant’s waste treatment and disposal procedures. Making sure that wastes are converted into less harmful substances and/or processed into other forms that have smaller environmental impacts has always been a goal of plant designers ever since the environment’s condition became a major industrial issue. The significant cost savings in doing so attracted more and more companies to continually devise solutions to pollution treatment problems.

As beneficial as it may be to a company and to the environment, waste minimization by this method is not necessarily the best way for a chemical plant to be “green”. Friedlander’s (1989) paper regarding this matter stresses the need to address pollution problems at the source, in contrast with addressing such problems directly at the waste stream end of the plant, although he also claimed that a design procedure for doing this is not available.

This claim, however, may not exactly be true. Read More

Water Pinch Analysis: A Shining Example of Mass Process Integration

Last Friday, the class discussed another aspect of process integration: mass integration. Specifically, what had been discussed are the direct recycle network and its constraints, such as the equipment, corrosion of materials, solubility, monitoring, and constraint propagation, and the mass recycle and exchange pinch. However, the significance of this to the industry has not been discussed. Our journal entry for this week deals with this as we talk about one type of mass integration approach, namely, water pinch analysis, and its corresponding significance to the industry.

Read More

A Note on Heat Exchange Networks

Optimization of processes is important in process design as it can affect the operational and capital cost and the operational safety of the plant. In this week, heat exchanger networks and heat integration are discussed in class to minimize the heat wasted in heating and cooling process.
In the homework given last week, there are 2 distillation columns operated in series. Both of them have reboilers and total condensers. The bottom products are put to other processing units. The overhead product of the first column is the feed for the second cooler and the overhead product of the second column is the purified product. The feed is preheated and the product is cooled.
The table below is the stream and their duties, together with the source and target temperature.
Capture

The pinch point is identified at T = 70°C/ t = 60°C. The minimum heating requirement is 2.3 MW while the minimum cooling requirement is 1.6 MW.
Since streams 4 and 5 are above the pinch point, they have to be heated externally.
Only stream 1 is heated by the cooling streams. Stream 6 can also be heated by Stream 1 however due to a lower heat capacity and being an added burden because of its low duty, it is not an option for heat integration.
Therefore, the possible choices are:
(1) Stream 2 only
(2) Stream 3 only
With that in mind, our group chose stream 2 in heating stream 1 because it has a higher heat capacity and temperature difference, thus a lower heat transfer area. While stream 1 will reach the target temperature of 50°C, stream 2 can only reach 63°C, thus an additional utility is added to further cool stream 2 to 60°C.
Additional factors taken into account such as compatibility of process chemicals and distance between equipment which involves piping of materials, but it is not asked in determining the best process in transferring heat throughout the system.

Hot n Cold: The Wonders of Heat Integration

This week, we got to talk about the kind of technical topic of process integration. Well, at least, we started with heat integration in particular. Heat integration, commonly known as pinch technology or pinch analysis, isn’t something new to us 5th year chemical engineering students. In one way or another, we have talked about it in our previous heat and mass transfer design course a year ago. Basically, pinch analysis is a design technique originally devised by a Ph.D. student in the University of Leeds back in 1977 that aims to minimize the energy consumption and maximize the heat recovery of a given process (Ebrahim & Kawari, 2000). It involves determining how process streams and equipment should be arranged in such a way that the heat given off by a stream in an equipment (usually a heat exchanger) can be utilized by another stream. This is executed with the minimization of utility demand and increase in profit in mind.

You’re probably wondering how this topic fits in with our environmental engineering design course. Don’t worry, we’ll get to that in a while. First, let’s get into the fundamental nature of process integration. Obviously, we have to know what it’s about in the first place for us to know how it would aid us in considering the environment in our designs. Read More

The “Other” Responsibility of a Chemical Engineer

Ever since I have had an experience of the Chemical Engineering subjects, I have always regarded chemical engineering as a problem solving career. Everything has to be optimized: minimized raw material, maximize product through the use of the concepts from the foundation subjects: thermodynamics, transport, and kinetics. With ChE 141 and ChE 142 (Plant Design), I have been exposed to the economics of this career. It is important to optimize the process, but it is also important that profit will come from this. Capital cost and operational costs are considered before fully establishing a design concept for any equipment and the overall plant. Basically, the entirety of the project rely on the profitability. Having taken the ChE 197 elective of Health, Safey, and Environment, our professor has emphasized over and over again that safety is of paramount importance over profit. No matter how profitable a project is, if it is highly hazardous, and if risk management is impossible, it is better to abandon the project. A ChE 190 seminar about the role of the Environmental Impact Assessment and Management Division Staff from the previous semester also emphasized this responsibility for a chemical engineer. Attending this ChE 198 Design for Environment elective has further cemented this paradigm.

I find it inspiring that there are countries that are already taking the initiative to create a culture of environmentally-friendly processes. There are more government monitoring and assessment happening to reduce emissions. In Europe, one example is the managing of carbon emissions among the countries in the European Union is the Emissions Trading Scheme. In the Philippines, waste generation is also being monitored by the government, as was discussed to us in a ChE 190 seminar, wherein the speakers were members of the Environmental Management Bureau of the Department of Environment and Natural Resources.

One of the speakers was Engr. Mary Therese Gonzales, a Technical Staff member of the Monitoring and Validating Section in the Environmental Impact Assessment and Management Division Staff of the Environmental Management Bureau of the Department of Environment and Natural Resources. She graduated from the University of the Philippines Los Banos with a degree in BS Agricultural Engineering. She discussed the Environmental Impact Assessment, a requirement for the industry before the construction on any plant or other infrastructure. It was highlighted that this was not a permit. Instead, this is a planning and management tool; a document made by the company itself, consisting of provisions on how they would manage all environmental consequences in the area: bio-physical or socio-economic. It is a commitment that they set for themselves, and promise to uphold. The EMB now inspects and assesses the area on a regular basis to check if the company is fulfilling its responsibilities.

After the talk, it made me realize that it is not the government’s job to maintain the environment. It is only there to monitor the industry, as they are the main sector that creates a large impact on the environment, may it be good or bad. The industry still bears the accountability in taking care of its surroundings. And I find the EIA as a symbol to this commitment of all the companies that are willing to take part in this duty. Thus, it is important that as future chemical engineers, we would also take part in this service not only to humanity but also to the environment. With the current lectures in ChE 198, I see that there are methods and heuristics wherein emissions can be managed by the industries. It can start through the design of the reactors, separation process, and the handling of fugitive emissions. Cooperation within the industries will also be a big help in this. Those that cannot afford to reduce emissions can be helped by other companies who can. Some companies also resort to indirect methods such as tree planting and investment on renewable energy.

Chemical engineering is not called the universal engineer for nothing, as a holistic view is needed to be a true chemical engineer. Yes, we are problem solvers, designing processes to manufacture products and solutions for human needs. Yes, we are business people, maximizing profit from the said products and solutions. But ultimately, we are also stewards of the environment, minimizing impact to the surroundings, mitigating wastes and emissions, and generating solutions to maintain and improve the environment. After all, we are not just engineers. We are chemical engineers.